Publications 2001-Present
|
82
Yoshinaka, Y.; Miller, S. A. “Bio-oil derived polyesteramides as water-degradable replacements for polyethylene”
Green Chemistry,
2025,
Published February 5, 2025.
https://doi.org/10.1039/D4GC05490C
Chemistry World News Article “Seed oil-based polymer should survive a day in the rain but degrade within years in the sea”, by Zifei Lu, February 10,
2025.
https://www.chemistryworld.com/news/4020936.article
Selected for the Cover of Green Chemistry (image coming soon)....
|
 |
|
81
Su, Y.-K.; Short, G. N.; Miller, S. A. “Renewable and water-degradable polyimide-esters from citric acid”
Green Chemistry,
2023,
25,
6200–6206.
https://doi.org/10.1039/D3GC01779F
|
 |
|
78
Simon, J.; Fliri, L.; Sapkota, J.; Ristolainen, M.; Miller, S. A.; Hummel, M.; Rosenau, T.; Potthast, A. “Reductive Amination of Dialdehyde Cellulose: Access to Renewable Thermoplastics”
Biomacromolecules,
2022,
24,
166–177.
https://doi.org/10.1021/acs.biomac.2c01022
|
 |
|
77
Diot-Néant, F.; Mouterde, L. M. M.; Veith, C.; Couvreur, J.; Miller, S. A.; Allais, F. “Sustainable One-Pot Synthesis and Polycondensation of a Levoglucosenone-Derived Cyclic Acetal Diol”
ACS Sustainable Chem. Eng.,
2022,
10,
10132–10143.
https://doi.org/10.1021/acssuschemeng.2c01362
|
 |
|
75
Su, Y.-K.; Coxwell, C. M.; Shen, S.; Miller, S. A. “Polyvinyl alcohol modification with sustainable ketones”
Polym. Chem.,
2021,
12,
4961-4973.
https://doi.org/10.1039/d1py00656h
|
 |
|
74
George, S.; Seepaul, R.; Geller, D.; Dwivedi, P.; DiLorenzo, N.; Altman, R.; Coppola, E.; Miller, S. A.; Bennett, R.; Johnston, G.; Streit, L.; Csonka, S.; Field, J.; Marois, J.; Wright, D.; Small, I.; Philippidis, G. P. “A regional inter-disciplinary partnership focusing on the development of a carinata-centered bioeconomy”
GCB Bioenergy,
2021,
13,
1018–1029.
https://doi.org/10.1111/gcbb.12828
|
 |
|
68
Nsengiyumva, O.; Miller, S. A. “Synthesis, characterization, and water-degradation of biorenewable polyesters derived from natural camphoric acid”
Green Chem.,
2019,
21,
973-978.
https://doi.org/10.1039/c8gc03990a
|
 |
|
67
Diot-Neant, F.; Rastoder, E.; Miller, S. A.; Allais, F. “Chemo-enzymatic synthesis and free radical polymerization of renewable acrylate monomers from cellulose-based lactones”
ACS Sustainable Chem. Eng.,
2018,
6,
17284–17293.
https://doi.org/10.1021/acssuschemeng.8b04707
|
 |
|
66
Short, G. N.; Nguyen, H. T. H.; Scheurle, P. I.; Miller, S. A. “Aromatic Polyesters from Biosuccinic Acid”
Polym. Chem.,
2018,
9,
4113-4119.
https://doi.org/10.1039/c8py00862k
|
 |
|
65
Moura, H. M.; Gibbons, N. L.; Miller, S. A.; Pastore, H. O. “2D-aluminum-modified solids as simultaneous support and cocatalyst for in situ polymerizations of olefins”
Journal of Catalysis,
2018,
362,
129-145.
https://doi.org/10.1016/j.jcat.2018.04.002
|
 |
|
63
Moura, H. M.; Gibbons, N. L.; Miller, S. A.; Pastore, H. O. “Tailoring 2D and 3D molecular sieves structures for polyolefin composites: do all roads lead to remarkable performances?”
Dalton Trans.,
2018,
47,
3128-3143.
http://dx.doi.org/10.1039/c7dt03734a
|
 |
|
60
Qi, P.; Chen, H.-L.; Nguyen, H. T. H.; Lin, C.-C.; Miller, S. A. “Synthesis of Biorenewable and Water-Degradable Polylactam Esters from Itaconic Acid”
Green Chem.,
2016,
18,
4170-4175.
http://dx.doi.org/10.1039/c6gc01081d
Back Cover Graphic for Green Chemistry, 2016, Issue 15
http://dx.doi.org/10.1039/C6GC90077A
|
 |
|
59
Rostagno, M.; Price, E. J.; Pemba, A. G.; Ghiriviga, I.; Abboud, K. A.; Miller, S. A. “Sustainable polyacetals from erythritol and bioaromatics”
J. Appl. Polym. Sci.,
2016,
133,
44089.
http://dx.doi.org/10.1002/app.44089
|
 |
|
57
Zhang, Z.; Nguyen, H. T. H.; Miller, S. A.; Ploskonka, A. M.; DeCoste, J. B.; Cohen, S. M. “polyMOFs as Water Tolerant Materials for Selective Carbon Dioxide Separations”
J. Am. Chem. Soc.
2016,
138,
920-925.
http://dx.doi.org/10.1021/jacs.5b11034
|
 |
|
55
Zakrzewska, S.; Komber, H.; Häussler, L.; Miller, S. A.; Nguyen, H. T. H.; Voit, B.; Schulze, U. “Controlled homo- and copolymerization of propene and 1-undecene catalyzed by post-metallocenes”,
Eur. Polymer J.
2015,
70,
104-117.
http://dx.doi.org/10.1016/j.eurpolymj.2015.07.009
|
 |
|
54
Nejabat, G.-R.; Nekoomanesh, M.; Arabi, H.; Salehi-Mobarakeh, H.; Zohuri, G.-H.; Mortazavi, S. M. M.; Ahmadjo, S.; Miller, S. A. “Study of Ziegler-Natta/(2-PhInd)2ZrCl2 hybrid catalysts performance in slurry propylene polymerization”,
Polyolefins Journal
2015,
2,
73-87.
http://poj.ippi.ac.ir/article_1145_341.html
|
|
|
53
Nguyen, H. T. H.; Suda, E. R.; Bradic, E. M.; Hvozdovich, J. A.; Miller, S. A. “Polyesters from Bio-Aromatics”, ACS Symposium Series,Green Polymer Chemistry III: Biobased Materials and Biocatalysis, eds. H. N. Cheng, R. Gross, and P. Smith 2015,
Vol. 1192,
Chapter 24,
401–409.
http://dx.doi.org/10.1021/bk-2015-1192.ch024
|
|
|
52
Zhang, Z.; Nguyen, H. T. H.; Miller, S. A.; Cohen, S. M. “polyMOFs: A Class of Interconvertible Polymer-Metal-Organic-Framework Hybrid Materials”,
Angew. Chem. Int. Ed.
2015,
54,
6152–6157.
http://dx.doi.org/10.1002/anie.201502733
Angewandte Chemie Frontispiece Graphic:
http://dx.doi.org/10.1002/anie.201582161
Chemistry World Research Editorial “Floppy polymer defies convention to form rigid framework”, by Simon Hadlington, April 30,
2015.
http://www.rsc.org/chemistryworld/2015/04/floppy-polymer-defies-convention-form-rigid-mof
Chemical & Engineering News Research Editorial “MOFs Made From Flexible Polymers Buck Conventional Wisdom”, by Mitch Jacoby, May 7,
2015.
http://cen.acs.org/articles/93/i19/MOFs-Made-Flexible-Polymers-Buck.html
http://www.cendigital.org/cendigital/20150511?sub_id=wGQv8dEDCk3P&folio=3#pg7
|
 |
|
48
Pemba, A. G.; Rostagno, M.; Lee, T. A.; Miller, S. A. “Cyclic and spirocyclic polyacetal ethers from lignin-based
aromatics”,
Polym. Chem.
2014,
5,
3214-3221.
http://dx.doi.org/10.1039/C4PY00178H
|
 |
|
47
Miller, S. A. “Sustainable polymers: replacing polymers derived from fossil fuels” (Editorial for Special Issue),
Polym. Chem.
2014,
5,
3117–3118.
http://dx.doi.org/10.1039/C4PY90017K
|
 |
|
43
Madkour, T. M.; Salem, S. A.; Miller, S. A. “The role of the deformational entropy in the miscibility of polymer blends investigated using a hybrid statistical mechanics and molecular dynamics model”
Phys. Chem. Chem. Phys.
2013,
15,
5982-5991.
http://dx.doi.org/10.1039/c3cp44536d
|
 |
|
42
Chai, J.; Abboud, K. A.; Miller, S. A. “Sterically expanded CGC catalysts: Substituent effects on ethylene and alpha-olefin polymerization”
Dalton Trans.
2013,
42,
9139-9147.
http://dx.doi.org/10.1039/C3DT50163A
|
 |
|
40
Pemba, A. G.; Flores, J. A; Miller, S. A. “Acetal Metathesis Polymerization (AMP): A method for synthesizing biorenewable polyacetals”
Green Chemistry
2013,
15,
325–329.
http://dx.doi.org/10.1039/C2GC36588J
|
 |
|
39
Nejabat, G. R.; Nekoomanesh, M.; Arabi, H.; Salehi-Mobarakeh, H.; Zohuri, G. H.; Omidvar, M.; Miller, S. A. “Synthesis and Microstructural Study of Stereoblock Elastomeric Polypropylenes from Metallocene Catalyst (2-PhInd)2ZrCl2 Activated with Cocatalyst Mixtures”
J. Polym. Sci. Part A: Polym. Chem.
2013,
51,
724–731.
http://dx.doi.org/10.1002/pola.26432
|
 |
|
39
Nejabat, G. R.; Nekoomanesh, M.; Arabi, H.; Salehi-Mobarakeh, H.; Zohuri, G. H.; Omidvar, M.; Miller, S. A. “Synthesis of Stereoblock Elastomeric Poly(propylene)s Using a (2-PhInd)2ZrCl2 Metallocene Catalyst in the Presence of Co-Catalyst Mixtures, 1–Study of Activity and Molecular Weight”
Macromol. React. Eng.
2012,
6,
523–529.
http://dx.doi.org/10.1002/mren.201200046
|
 |
|
37
Chen, H.-Y.; Mialon, L.; Abboud, K. A.; Miller, S. A. "Comparative Study of Lactide Polymerization with Lithium, Sodium, Magnesium, and Calcium Complexes of BHT"
Organometallics
2012,
31,
5252–5261.
http://dx.doi.org/10.1021/om300121c
|
 |
|
36
Zohuri, G.H.; Albahily, K.; Schwerdtfeger, E.D.; Miller, S.A. Metallocene Alkene Polymerization Catalysts, In Polymer Science: A Comprehensive Reference, Vol. 3; Matyjaszewski, K.; Möller, M., Eds.-in-Chief; Elsevier: Amsterdam, 2012; pp. 673-231.
http://dx.doi.org/10.1016/B978-0-444-53349-4.00081-9
|
 |
|
34
Chen, H.-Y.; Peng, Y.-L.; Huang, T.-H.; Sutar, A. K.; Miller, S. A.; Lin, C.-C.
"Comparative study of lactide polymerization by zinc alkoxide complexes with a beta-diketiminato ligand bearing different substituents"
J. Mol. Cat. A: Chem.
2011,
339,
61-71.
http://dx.doi.org/10.1016/j.molcata.2011.02.013
|
 |
|
32
Schwerdtfeger, E. D.; Price, C. J.; Chai, J.; Miller, S. A.
"Tandem Catalyst System for Linear Low Density Polyethylene with Short and Long Branching"
Macromolecules
2010,
43,
4838-4842.
http://dx.doi.org/10.1021/ma100545q
|
 |
|
31
Ogle, J. W.; Miller, S. A.
"Electronically tunable N-heterocyclic carbene ligands: 1,3-diaryl vs. 4,5-diaryl substitution"
Chem. Commun.
2009,
5728-5730.
http://dx.doi.org/10.1039/b914732b
|
 |
|
29
Sun, L.; Liu, J.; Kirumakki, S. R.; Schwerdtfeger, E. D.; Howell, R. J.; Al-Bahily, K.; Miller, S. A.; Clearfield, A.; Sue, H.-J. "Polypropylene Nanocomposites Based on Designed Synthetic Nanoplatelets"
Chem. Mater.
2009,
21,
1154-1161.
http://dx.doi.org/10.1021/cm803024e
|
 |
|
27
Ruebush, L. E.; Grossman, E. L.; Miller, S. A.; North, S. W.; Schielack, J. F.; Simanek, E. E. “Scientists’ Perspective on Introducing Authentic Inquiry to High School Teachers During an Intensive Three-Week Summer Professional Development Experience”
School Science and Mathematics
2009,
109(3),
162–174.
http://dx.doi.org/10.1111/j.1949-8594.2009.tb17952.x
|
 |
|
26
Ogle, J. W.; Zhang, J.; Reibenspies, J. H.; Abboud, K. A.; Miller, S. A.
"Synthesis of Electronically Diverse Tetraarylimidazolylidene Carbenes via Catalytic Aldimine Coupling"
Org. Lett.
2008,
10,
3677-3680.
http://dx.doi.org/10.1021/ol8012765
|
 |
|
25
Price, C. J.; Zeits, P. D.; Reibenspies, J. H.; Miller, S. A. "Octamethyloctahydrodibenzofluorenyl: Electronic Comparisons Between a Sterically Expanded Ligand and its Cyclopentadienyl Analogues"
Organometallics
2008,
27,
3722-3727.
http://dx.doi.org/10.1021/om8001526
|
 |
|
24
Schwerdtfeger, E. D.; Irwin, L. J.; Miller, S. A. "Highly Branched Polyethylene from Ethylene Alone via a Single Zirconium-Based Catalyst"
Macromolecules
2008,
41,
1080-1085.
http://dx.doi.org/10.1021/ma702213c
|
 |
|
23
Ilg, A. D.; Price, C. J.; Miller, S. A. "Linear Low Density Polyoxymethylene versus Linear Low Density Polyethylene Macromolecules"
Macromolecules
2007,
40,
7739-7741.
http://dx.doi.org/10.1021/ma702066y
|
 |
|
22
Chen, H.-Y.; Zhang, J.; Lin, C.-C.; Reibenspies, J. H.; Miller, S. A. "Efficient and controlled polymerization of lactide under mild conditions with a sodium-based catalyst"
Green Chem.
2007,
9,
1038-1040.
http://dx.doi.org/10.1039/b705622b
|
 |
|
20
Schwerdtfeger, E. D.; Miller, S. A. "Intrinsic Branching Effects in Syndiotactic Copolymers of Propylene and Higher alpha-Olefins"
Macromolecules
2007,
40,
5662-5668.
http://dx.doi.org/10.1021/ma070060q
|
 |
|
19
Irwin, L. J.; Zeits, P. D.; Reibenspies, J. H.; Miller, S. A. "Diffuse Diffraction from Parallel/Antiparallel Metallocene Pillars"
Organometallics
2007,
26,
1129-1133.
http://dx.doi.org/10.1021/om060435g
|
 |
|
18
Price, C. J.; Irwin, L. J.; Aubry, D. A.; Miller, S. A. "Fluorenyl Containing Catalysts for Stereoselective Propylene Polymerization" in Stereoselective Polymerization with Single Site Catalysts; Canich, J. M.; Baugh, L. S., Eds.; CRC Press, 2007, pp. 37-82, ISBN: 1574445790.
http://dx.doi.org/10.1201/9781420017083.ch2
http://www.crcpress.com/product/isbn/9781574445794
|
 |
|
17
Grill, J. M.; Ogle, J. W.; Miller, S. A. "An Efficient and Practical System for the Catalytic Oxidation of Alcohols, Aldehydes, and alpha,beta-Unsaturated Carboxylic Acids"
J. Org. Chem.
2006,
71,
9291-9296.
http://dx.doi.org/10.1021/jo0612574
|
 |
|
16
Price, C. J.; Reich, B. J. E.; Miller, S. A. "Thermodynamic and Kinetic Considerations in the Copolymerization of Ethylene and Carbon Dioxide"
Macromolecules
2006,
39,
2751-2756.
http://dx.doi.org/10.1021/ma052697k
|
 |
|
14
Reich, B. J. E.; Greenwald, E. E.; Justice, A. K.; Beckstead, B. T.; Reibenspies, J. H.; North, S. W.; Miller, S. A. "Ene-diamine versus Imine-amine Isomeric Preferences"
J. Org. Chem.
2005,
70,
8409-8416.
http://dx.doi.org/10.1021/jo051102g
|
 |
|
13
Greenwald, E. E.; Park, J.; Anderson, K. C.; Kim, H.; Reich, B. J. E.; Miller, S. A.; Zhang, R.; North, S. W. "The OH-Initiated Oxidation of 1,3-Butadiene in the Presence of O2 and NO: A Photolytic Route To Study Isomeric Selective Reactivity"
J. Phys. Chem. A
2005,
109,
7915-7922.
http://dx.doi.org/10.1021/jp051545o
|
 |
|
12
Irwin, L. J.; Reibenspies, J. H.; Miller, S. A. "Synthesis and characterization of sterically expanded ansa-η1-fluorenyl-amido complexes"
Polyhedron
2005,
24,
1314-1324. Special issue: Ansa Metallocenes and Related Compounds.
http://dx.doi.org/10.1016/j.poly.2005.03.011
|
 |
|
11
Irwin, L. J.; Miller, S. A. "Unprecedented Syndioselectivity and Syndiotactic Polyolefin Melting Temperature: Polypropylene and Poly(4-methyl-1-pentene) from a Highly Active, Sterically Expanded η1-Fluorenyl-η1-Amido Zirconium Complex"
J. Am. Chem. Soc.
2005,
127,
9972-9973.
http://dx.doi.org/10.1021/ja052256g
|
 |
|
10
Grill, J. M.; Reibenspies, J. H.; Miller, S. A. "Racemic and chiral expanded salen-type complexes derived from biphenol and binaphthol: Salbip and salbin"
J. Organomet. Chem.
2005,
690,
3009-3017.
http://dx.doi.org/10.1016/j.jorganchem.2005.03.034
|
 |
|
9
Irwin, L. J.; Reibenspies, J. H.; Miller, S. A. "A Sterically Expanded “Constrained Geometry Catalyst” for Highly Active Olefin Polymerization and Copolymerization: An Unyielding Comonomer Effect"
J. Am. Chem. Soc.
2004,
126,
16716-16717.
http://dx.doi.org/10.1021/ja044678g
|
 |
|
7
Reich, B. J. E.; Justice, A. K.; Beckstead, B. T.; Reibenspies, J. H.; Miller, S. A. "Cyanide-Catalyzed Cyclizations via Aldimine Coupling"
J. Org. Chem.
2004,
69,
1357-1359.
http://dx.doi.org/10.1021/jo035245j
|
 |
Patents
|
8
Miller, S. A.; Mialon, L. "Poly(dihydroferulic acid): A biorenewable polyethylene terephthalate mimic derived from lignin and acetic acid and Copolymers Thereof" U.S. Patent 9,624,340, 2017 (University of Florida).
https://patents.google.com/patent/US9624340
|
 |
|
7
Polyglycolic acid and copolymers thereof from C1 Feedstocks. Inventors: Stephen A. Miller, Alexander G. Pemba, Ersen Gokturk. U.S. Patent 9,303,118; Priority Date March 8th, 2012; Publication Date April 5, 2016. (University of Florida).
https://www.google.com/patents/US9303118
|
 |
|
5
Miller, S. A.; Mialon, L. "Poly(dihydroferulic acid): A biorenewable polyethylene terephthalate mimic derived from lignin and acetic acid and Copolymers Thereof" U.S. Patent 9,080,011, 2015 (University of Florida).
https://patents.google.com/patent/US9080011
|
 |
|
3
Miller, S. A.; Irwin, L. J. "Novel Catalyst Systems for High Activity and Stereoselectivity in the Homopolymerization and Copolymerization of Olefins" U.S. Patent 7,214,749, 2007 (Texas A&M University).
https://patents.google.com/patent/US7214749
|
 |
Postdoctoral Publications with R. R. Schrock at the Massachusetts Institute of Technology
|
6
Schrock, R. R.; Jamieson, J. Y.; Dolman, S. J.; Miller, S. A.; Bonitatebus, P. J.; Hoveyda, A. H. "New Chiral Molybdenum Catalysts for Asymmetric Olefin Metathesis that Contain 3,3’-Disubstituted Octahydrobinaphtholate or 2,6-Dichlorophenylimido Ligands"
Organometallics
2002,
21,
409-417.
http://dx.doi.org/10.1021/om0107441
|
 |
Graduate Publications with J. E. Bercaw at the California Institute of Technology
|
5
Miller, S. A.; Bercaw, J. E. "Mechanism of Isotactic Polypropylene Formation with C1-symmetric Metallocene Catalysts"
Organometallics
2006,
25,
3576-3592.
http://dx.doi.org/10.1021/om050841k
|
 |
|
4
Miller, S. A.; Bercaw, J. E. "Highly Stereoregular Syndiotactic Polypropylene Formation with Metallocene Catalysts via Influence of Distal Ligand Substituents"
Organometallics
2004,
23,
1777-1789.
http://dx.doi.org/10.1021/om030333f
|
 |
|
3
Miller, S. A.; Bercaw, J. E. "Isotactic-Hemiisotactic Polypropylene from C1-Symmetric, ansa-Metallocene Catalysts: A New Strategy for the Synthesis of Elastomeric Polypropylene"
Organometallics
2002,
21,
934-945.
http://dx.doi.org/10.1021/om010788+
|
 |
|
2
Miller, S. A.; Bercaw, J. E. "Aminofluorenyl-Pentamethylcyclopentadienyl and Bis(aminofluorenyl) Derivatives of Group 4 Metals Organometallics"
Organometallics
2000,
19,
5608-5613.
http://dx.doi.org/10.1021/om000723r
|
 |
Undergraduate Publications with R. M. Waymouth at Stanford University
|
|
| |
|
